Frieworks is much better suited for this task imo. While photoshop is the bestest at many things (I have CS 2) even with my years of doing photo restorations etc.. I find Fireworks to be THE BEST for web comps, design, and icon/logo creation. But thats me. Also slicing things up in Fireworks is just uber nice the way it all works. FW is a web designing app, PS is not imo. Now if you are talking general design, dtp etc.. Photoshop all the way.

__________________
I hate IE 6. Just sayin....