Excel!? Are you serious?
Just checking we're on the same wavelength here, you're talking about visual structure / page layout?
Personally, I use Photoshop (Elements) and I know a lot of others do too. If the CS version is bit over budget (I think the going rate is £600+-

),
Elements is an excellent alternative.
The next best (some argue 'as good as') alternative is the
GIMP - and it's open source!