I'm using Dreamweaver CS3. Any reason why I should use TopStyle instead? I think the .css-support in DW is great, although I can't compare it with anything :P

So, a little resume: Use photoshop to create the layout, then cut it up by hand and try to use only the images like the rounded corders.
Than use dreamweaver or TopStyle to create a slick .css-file.
Also use the CSS for creating borders, buttons and background coloring.

Am I right so far?